Headspace Analysis From Innovatech Labs

Headspace analysis a means of separating the volatile material(s) from a liquid or solid prior to analysis by gas chromatography/mass spectrometry GC/MS. 

As one of the leading materials analysis labs, Innovatech Labs uses two basic means of collecting the volatiles for analysis:  Dynamic Headspace and Static Headspace. Dynamic headspace uses a "purge and trap" method to collect the sample on a sorbent material, and then the sample is flushed onto the column for analysis by GC/MS.  The sample is heated in a sealed environment and the gases are removed from the vial for analysis in static headspace analysis. For more information on the two types of sampling see the text below. 

Our experienced materials testing analysts can help you decide which technique is best suited for your application and help explain what the data means once it is collected.  To discuss your specific headspace or materials analysis needs call us at the phone numbers on the left or by email.

Dynamic Headspace - DHS is a form of headspace analysis that utilizes a "purge and trap" method to collect and concentrate outgassed materials for analysis by GC/MS.  In this method, the sample is purged with ultra pure nitrogen while being heated in a Teflon vessel.  As the nitrogen stream exits the vessel it passes through a thermal desorption tube filled with an adsorbent material. The outgassed products are collected onto the adsorbent material.  Following the predetermined collection time, the tubes are transferred to a thermal desorption unit which is inline with the gas chromatograph and mass selective detector (GC/MS).

The thermal desorption unit heats the individual tubes while a flow of gas is applied through the tube.  The collected materials are flushed from the sorbent material and collected onto a cold trap within the thermal desorption unit.  After the entire sample has been purged from the sample tube and collected on the cold trap, the cold trap is heated rapidly.  The collected materials are then swept from the cold trap into the GC/MS for analysis as a volatile material. 

The typical sensitivity for compounds analyzed by DHS is nanogram per gram.

Static Headspace - In SHS static headspace analysis, a liquid or solid sample is placed into a vial, sealed, and heated to a specific temperature.  All of the components that are volatile at or below the pre-set temperature escape from the sample to form a gaseous "headspace" above the sample.  The term "static headspace" refers to the sealed environment in which the outgassed products are collected.

After a certain period of time, the headspace gas is extracted from the vial and injected into a gas chromatograph which separates the various components of the sample based on size and/or polarity.  The separated components then go into a mass selective detector.  The resulting mass spectrum allows for the identification of the components using standard reference libraries.

Static headspace analysis is an ideal choice for volatile compounds, such as residual solvents or low molecular weight additives. The sensitivity for static headspace is typically in the sub microgram range, however this is dependent on the volatility of the compounds.